Hi, I already done integration of SMS API's using php. I am expert in php,mysql,Zend,Codeigniter,Jquery,Javascript etc. I would recommend to use Zend framework for your application because it is secure and using it we can maintain coding standard for future enhancements. Also find my attached portfolio for consideration.
Let me know if you have any questions.
Thank you for your time.
Regadrs,
Irfan